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Long term phase separation dynamics in liquid crystal-enriched microdroplets obtained from binary fluid mixtures

Patel, Mehzabin; Shimizu, Seishi; Bates, Martin; Fernandez-Nieves, Alberto; Guldin, Stefan; (2022) Long term phase separation dynamics in liquid crystal-enriched microdroplets obtained from binary fluid mixtures. American Chemical Society (ACS): Washington, D.C., USA. Green open access

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Abstract

The dynamics of long term phase separation in binary liquid mixtures remains a subject of fundamental interest. Here, we study a binary liquid mixture, where the minority phase is confined to a liquid crystal (LC)-rich droplet, by investigating the evolution of size, defect and mesogen alignment over time. We track the binary liquid mixture evolving towards equilibrium by visualising the configuration of the liquid crystal droplet through polarisation microscopy. We compare our experimental findings with computational simulations and elucidate the bulk vs microdroplet difference based on the thermodynamics of phase separation. Our work provides insights on how phase transitions on the microscale can deviate from bulk ph

Type: Working / discussion paper
Title: Long term phase separation dynamics in liquid crystal-enriched microdroplets obtained from binary fluid mixtures
Open access status: An open access version is available from UCL Discovery
DOI: 10.26434/chemrxiv-2022-pc12b
Publisher version: https://doi.org/10.26434/chemrxiv-2022-pc12b
Language: English
Additional information: © The Author 2022. Original content in this pre-print is licensed under the terms of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) Licence (https://creativecommons.org/licenses/by-nc-nd/4.0/).
Keywords: liquid crystal droplets, binary liquid mixtures, phase separation, phase behaviour, confinement
UCL classification: UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL
URI: https://discovery.ucl.ac.uk/id/eprint/10157366
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