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The Decisive Role Played by Graphene Nanoplatelets on Improving the Tribological Performance of Y2o3-al2o3-sio2 Glass Coatings

Gomez-Gomez, A; Nistal, A; Garcia, E; Isabel Osendi, M; Belmonte, M; Miranzo, P; (2016) The Decisive Role Played by Graphene Nanoplatelets on Improving the Tribological Performance of Y2o3-al2o3-sio2 Glass Coatings. Materials & Design , 112 pp. 449-455. 10.1016/j.matdes.2016.09.056. Green open access

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Abstract

Graphene nanoplatelets (GNPs) have proved to be effective fillers for enhancing the mechanical and tribological properties of bulk ceramics and glasses, also with the added benefit of developing electrical and thermal functionalities. Similarly, enhanced transport performance has recently been shown for glass-ceramics coatings of the Y2O3-Al2O3-SiO2 (YAS) system containing a small amount of GNP fillers, intended for applications in the aerospace industry. In the present work, the wear and friction behaviour of GNP/YAS coatings –containing 0, 1.2 and 2.3 wt.% GNPs- on silicon carbide substrates is evaluated. The flame spraying process used for coating fabrication induces a structure of splats oriented parallel to the substrate with GNPs located at the inter-splat boundaries forming a connected network of platelets mainly oriented parallel to the surface as well. Unlubricated ball–on-plate reciprocating wear tests show that both the friction coefficient and the wear rate decreased by 35% and 65%, respectively, for 2.3 wt.% of GNPs. A wear mechanism for GNP/YAS coatings based on both the progressive exfoliation of the graphene sheets and the effect of the GNPs on preventing crack propagation within the coating is proposed.

Type: Article
Title: The Decisive Role Played by Graphene Nanoplatelets on Improving the Tribological Performance of Y2o3-al2o3-sio2 Glass Coatings
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.matdes.2016.09.056
Publisher version: https://doi.org/10.1016/j.matdes.2016.09.056
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: Graphene, Glass, Coatings, Thermal spray, Wear, Friction
UCL classification: UCL
UCL > Provost and Vice Provost Offices
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > MAPS Faculty Office
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > MAPS Faculty Office > Institute for Materials Discovery
URI: https://discovery.ucl.ac.uk/id/eprint/10059416
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