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Revisiting the structure of the p(4x4) surface oxide on Ag(111)

Schnadt, J; Michaelides, A; Knudsen, J; Vang, RT; Reuter, K; Laegsgaard, E; Scheffler, M; (2006) Revisiting the structure of the p(4x4) surface oxide on Ag(111). PHYS REV LETT , 96 (14) , Article 146101. 10.1103/PhysRevLett.96.146101. Green open access

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Abstract

Scanning tunneling microscopy (STM) and density-functional theory are used to reexamine the structure of the renowned p(4x4)-O/Ag(111) surface oxide. The accepted structural model [C. I. Carlisle , Phys. Rev. Lett. 84, 3899 (2000)] is incompatible with the enhanced resolution of the current STM measurements. An "Ag-6 model" is proposed that is more stable than its predecessor and accounts for the coexistence of the p(4x4) and a novel c(3x5 root 3)rect phase. This coexistence is an indication of the dynamic complexity of the system that until now has not been appreciated.

Type: Article
Title: Revisiting the structure of the p(4x4) surface oxide on Ag(111)
Open access status: An open access version is available from UCL Discovery
DOI: 10.1103/PhysRevLett.96.146101
Publisher version: http://dx.doi.org/10.1103/PhysRevLett.96.146101
Language: English
Additional information: © 2006 The American Physical Society
Keywords: OXYGEN, CHEMISORPTION, MICROSCOPE, TRANSITION, ADSORPTION, INSIGHTS, FILM
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery.ucl.ac.uk/id/eprint/9326
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