Desrat, S;
van de Weghe, P;
(2009)
Intramolecular Imino Diels-Alder Reaction: Progress toward the Synthesis of Uncialamycin.
Journal of Organic Chemistry
, 74
(17)
6728 - 6734.
10.1021/jo901291t.
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Abstract
We herein described an intramolecular imino Diels-Alder reaction promoted with BF3.OEt2/DDQ affording substituted quinolines. Using this procedure, we prepared the chiral quitioline moiety of the uncialamycin, a new enediyne natural product.
| Type: | Article |
|---|---|
| Title: | Intramolecular Imino Diels-Alder Reaction: Progress toward the Synthesis of Uncialamycin |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1021/jo901291t |
| Publisher version: | http://dx.doi.org/10.1021/jo901291t |
| Language: | English |
| Additional information: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/jo901291t |
| Keywords: | QUINOLINES, ACID, CYCLIZATION, MARTINELLINE, ALCOHOLS, KETONES, DESIGN |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences |
| URI: | https://discovery.ucl.ac.uk/id/eprint/680369 |
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