O'Malley, AJ;
Parker, SF;
Chutia, A;
Farrow, MR;
Silverwood, IP;
García-Sakai, V;
Catlow, CR;
(2016)
Room temperature methoxylation in zeolites: insight into a key step of the methanol-to-hydrocarbons process.
Chemical Communications
, 52
(14)
pp. 2897-2900.
10.1039/c5cc08956e.
Preview |
Text
c5cc08956e.pdf - Published Version Download (2MB) | Preview |
Abstract
Neutron scattering methods observed complete room temperature conversion of methanol to framework methoxy in a commercial sample of methanol-to-hydrocarbons (MTH) catalyst H-ZSM-5, evidenced by methanol immobility and vibrational spectra matched by ab initio calculations. No methoxylation was observed in a commercial HY sample, attributed to the dealumination involved in high silica HY synthesis.
Type: | Article |
---|---|
Title: | Room temperature methoxylation in zeolites: insight into a key step of the methanol-to-hydrocarbons process |
Location: | England |
Open access status: | An open access version is available from UCL Discovery |
DOI: | 10.1039/c5cc08956e |
Publisher version: | http://dx.doi.org/10.1039/c5cc08956e |
Language: | English |
Additional information: | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
URI: | https://discovery.ucl.ac.uk/id/eprint/1486826 |
Archive Staff Only
View Item |