Maurellis, AN; Lang, R; Williams, JE; van der Zande, WJ; Smith, K; Newnham, DA; Tennyson, J; Maurellis, AN; Lang, R; Williams, JE; van der Zande, WJ; Smith, K; Newnham, DA; Tennyson, J; Tolchenov, RN; - view fewer (2003) The impact of new water vapor spectroscopy on satellite retrievals. In: CamyPeyret, C and Vigasin, AA, (eds.) UNSPECIFIED (259 - 272). SPRINGER

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Abstract

Water vapor, arguably the most important trace gas constituent of Earth atmospheric physics, is also both a retrieval goal and a hindrance in the retrievals of other trace gases from nadir-measuring satellite spectrometers. This is because the atmospherically-attenuated solar spectrum in the visible and shortwave infrared is littered with water vapor bands. The recent plethora of water vapor spectroscopy databases in this spectral region has prompted us to study their utility in satellite retrievals. We consider water vapor spectroscopy compiled from four sources including new spectroscopy due to University College London and Imperial College London. Radiative transfer models of satellite measurements, in combination with accurate retrieval techniques, are quite sensitive to the accuracy and completeness of the water vapor spectroscopy. Notwithstanding the high degree of variability of a number of different factors in satellite measurements we show that retrievals are sensitive to database differences which suggests that our knowledge of water vapor spectroscopy is not as yet complete. In addition, new laboratory measurements indicate that the role of both the far-line wings of water vapor and the cumulative effect of many weak lines each have an important role to play in forming the so-called continuum.

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