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Performance and Cost Analysis of Pressure Swing Adsorption for Recovery of H2, CO, and CO2 from Steelworks Off-Gases

Bashir, Fidal I; Porter, Richard TJ; Catalanotti, Elena; Mahgerefteh, Haroun; (2025) Performance and Cost Analysis of Pressure Swing Adsorption for Recovery of H2, CO, and CO2 from Steelworks Off-Gases. Energies , 18 (10) , Article 2440. 10.3390/en18102440. Green open access

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Abstract

The conceptual design and techno-economic assessment of Pressure Swing Adsorption (PSA) for the recovery of H2, CO2, and CO from steel making Blast Furnace-Basic Oxygen Furnace and Coke Oven off-gases, major contributors to anthropogenic carbon emissions, are presented. Three PSA units are modeled on Aspen Adsorption V14, each utilising dedicated adsorbents and configurations tailored for the target gas. Model validation is successfully conducted by comparing breakthrough simulation results with experimental data. The simulation results demonstrate that the PSA systems effectively separate H2 (99.3% purity, 80% recovery), CO (98% purity, 87% recovery), and CO2 (96.9% purity, 75% recovery) from steelmaking off-gases. Meanwhile, the techno-economic assessment indicates that the PSA systems are economically viable, with competitive costs of £2768/tH2, £52.78/tCO, and £16.89/tCO2 captured, making them an effective solution for gas separation in the steel industry.

Type: Article
Title: Performance and Cost Analysis of Pressure Swing Adsorption for Recovery of H2, CO, and CO2 from Steelworks Off-Gases
Open access status: An open access version is available from UCL Discovery
DOI: 10.3390/en18102440
Publisher version: https://doi.org/10.3390/en18102440
Language: English
Additional information: Copyright © 2025 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Keywords: Adsorption; pressure swing adsorption; vacuum swing adsorption; process simulation; techno-economic analysis
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering
URI: https://discovery.ucl.ac.uk/id/eprint/10219449
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