Wang, Jingyan;
Hwang, Gi Byoung;
Knapp, Caroline E;
Wilson, Daniel WN;
(2024)
Reversible CO₂ insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane.
Chemical Communications
10.1039/D4CC04798B.
(In press).
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Abstract
The reversible insertion of carbon dioxide into the silicon–nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO₂ can be stored for extended periods and is only released upon heating to 133 °C.
| Type: | Article |
|---|---|
| Title: | Reversible CO₂ insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane |
| Location: | England |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/D4CC04798B |
| Publisher version: | https://doi.org/10.1039/D4CC04798B |
| Language: | English |
| Additional information: | © The Author(s), 2024. This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY 4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. https://creativecommons.org/licenses/by/4.0/ |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10199023 |
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