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CFD Modelling of Mercury Behaviour in Air-coal and Oxy-coal Combustion Systems

Gharebaghi, Maryam; Hughes, Kevin; Ma, Lin; Porter, Richard; Pourkashanian, Mohamed; Williams, Alan; (2011) CFD Modelling of Mercury Behaviour in Air-coal and Oxy-coal Combustion Systems. In: Proceedings of the 2nd OxyFuel Combustion Conference. OxyFuel Combustion Conference: Queensland, Australia. Green open access

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Abstract

In this study, a mechanism for mercury chlorination in flue gases and fly ash particles resulting from the combustion of pulverised coal is presented. A reduced gas-phase reaction mechanism is combined with mercury heterogeneous oxidation on the fly ash particles. The mechanism is used in an advanced CFD model of a pilot-scale test facility and is validated by comparison to available experimental data for air-coal combustion conditions. The model is then used to simulate mercury speciation under oxy-coal combustion conditions. This approach aims to provide an improved prediction of mercury speciation from coal-fired power plants and to elucidate the changes to mercury speciation encountered during oxy–coal combustion.

Type: Proceedings paper
Title: CFD Modelling of Mercury Behaviour in Air-coal and Oxy-coal Combustion Systems
Event: 2nd OxyFuel Combustion Conference
Location: Yeppoon
Dates: 12 Sep 2010 - 16 Sep 2010
Open access status: An open access version is available from UCL Discovery
Publisher version: https://ieaghg.org/
Language: English
Additional information: This version is the version of record. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: Oxy-coal combustion, mercury speciation, CFD modelling
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering
URI: https://discovery.ucl.ac.uk/id/eprint/10183591
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