Zhang, L; Huang, J; Guo, H; Ge, L; Tian, Z; Zhang, M; Wang, J; ... Lai, F; + view all Zhang, L; Huang, J; Guo, H; Ge, L; Tian, Z; Zhang, M; Wang, J; He, G; Liu, T; Hofkens, J; Brett, DJL; Lai, F; - view fewer (2023) Tuning Ion Transport at the Anode-Electrolyte Interface via a Sulfonate-Rich Ion-Exchange Layer for Durable Zinc-Iodine Batteries. Advanced Energy Materials , 13 (13) , Article 2203790. 10.1002/aenm.202203790.

Preview

Text He_Manuscript.pdf Download (1MB) | Preview

Abstract

Rechargeable aqueous zinc-iodine batteries (ZIBs) are considered a promising newly-developing energy-storage system, but the corrosion and dendritic growth occurring on the anode seriously hinder their future application. Here, the corrosion mechanism of polyiodide is revealed in detail, showing that it can spontaneously react with zinc and cause rapid battery failure. To address this issue, a sulfonate-rich ion-exchange layer (SC-PSS) is purposely constructed to modulate the transport and reaction chemistry of polyiodide and Zn2+ at the zinc/electrolyte interface. The resulting ZIBs can work properly over 6000 cycles with high-capacity retention (90.2%) and reversibility (99.89%). Theoretical calculations and experimental characterization reveal that the SC-PPS layer blocks polyiodide permeation through electrostatic repulsion, while facilitating desolvation of Zn(H2O)62+ and restricting undesirable 2D diffusion of Zn2+ by chemisorption.

Download activity - last month

Export as XMLCSVJSON

Download activity - last 12 months

Export as JSONCSVXML

Downloads by country - last 12 months

Export as XMLCSVJSON

Archive Staff Only

View Item