Chen, Guanxu;
Chen, Jintao;
Parkin, Ivan P;
He, Guanjie;
Miller, Thomas S;
(2022)
Pseudohexagonal Nb2O5-Decorated Carbon Nanotubes as a High-Performance Composite Anode for Sodium Ion Batteries.
ChemElectroChem
10.1002/celc.202200800.
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Abstract
Pseudohexagonal Nb2O5 (TT-Nb2O5) has been applied in sodium ion batteries (SIBs) for the first time. Lower synthesis temperatures, improved conductivity and stability were achieved by the introduction of a designed carbon framework. The TT-Nb2O5/carbon nanotube composite exhibits high specific capacity (135 mAh g−1 at 0.2 A g−1) in long cycles and good rate capability (53 mAh g−1 at high current density of 5 A g−1). The outstanding electrochemical performance is attributed to the superior electrical conductivity and connectivity, optimal mass transport conditions and the mechanical strength and durability established by the strongly linked TT-Nb2O5 and MWCNT network. This study provides a cost-effective route to the application of Nb2O5 in SIBs.
Type: | Article |
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Title: | Pseudohexagonal Nb2O5-Decorated Carbon Nanotubes as a High-Performance Composite Anode for Sodium Ion Batteries |
Open access status: | An open access version is available from UCL Discovery |
DOI: | 10.1002/celc.202200800 |
Publisher version: | https://doi.org/10.1002/celc.202200800 |
Language: | English |
Additional information: | © 2022 The Authors. ChemElectroChem published by Wiley-VCH GmbH This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
Keywords: | Battery anode, Carbon nanomaterials, NIB, Niobium oxide, SIB |
UCL classification: | UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering UCL > Provost and Vice Provost Offices > UCL BEAMS UCL UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences |
URI: | https://discovery.ucl.ac.uk/id/eprint/10157560 |
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