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Role of blend ratio in bulk heterojunction organic retinomorphic sensors

Zhang, Xueqiao; Labram, John G; (2022) Role of blend ratio in bulk heterojunction organic retinomorphic sensors. Journal of Materials Chemistry C 10.1039/d2tc02048c. (In press). Green open access

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Abstract

Conventional image sensors are designed to digitally reproduce every aspect of the visual field; in general representing brighter regions of a scene as brighter regions in an image. While the benefits of detecting and representing light in this way are obvious, limitations imposed by processing power and frame rate place a cap on the speed at which moving objects can be identified. An emerging alternative strategy is to use sensors which output a signal only in response to changes in light intensity, hence inherently identifying movement by design. These so-called retinomorphic sensors are hoped to outperform conventional sensors for certain tasks, such as identification of moving objects. In this report, the working mechanism of retinomorphic sensors based on organic semiconductors as the active layer is probed. It is observed that the sign of the voltage signal is changed when electrode connections are reversed, suggesting our previous description of device behaviour was incomplete. By systematically varying the ratio of poly(3-hexylthiophene-2,5-diyl) (P3HT) to phenyl-C61-butyric acid methyl (PCBM) in the absorption layer, a maximum performance was observed when the ratio was 1 : 2 P3HT : PCBM, while pure P3HT and pure PCBM exhibited very weak signals.

Type: Article
Title: Role of blend ratio in bulk heterojunction organic retinomorphic sensors
Open access status: An open access version is available from UCL Discovery
DOI: 10.1039/d2tc02048c
Publisher version: https://doi.org/10.1039/d2tc02048c
Language: English
Additional information: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/).
UCL classification: UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Electronic and Electrical Eng
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL
URI: https://discovery.ucl.ac.uk/id/eprint/10154912
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