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Seed-Mediated, Shape-Controlled Synthesis Methods for Platinum-Based Electrocatalysts for the Oxygen Reduction Reaction—A Mini Review

Gray, DE; Munshi, T; Scowen, IJ; Brett, DJL; He, G; (2022) Seed-Mediated, Shape-Controlled Synthesis Methods for Platinum-Based Electrocatalysts for the Oxygen Reduction Reaction—A Mini Review. Frontiers in Chemistry , 10 , Article 865214. 10.3389/fchem.2022.865214. Green open access

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Abstract

Overcoming the slow oxygen reduction reaction (ORR) kinetics at the cathode of the hydrogen fuel cells requires the use of electrocatalysts containing expensive and scare platinum to achieve reasonable performance, hampering widespread use of the technology due to high material costs and sustainability issues. One option available to tackle this issue is to use new designs to create nanomaterials which achieve excellent electrocatalytic performances and long-lasting stabilities whilst using less platinum than is currently required. Reliably producing nanomaterials with predictable activities and stabilities using simple, safe, and scalable methods is an important research topic to the advancement of fuel cell technologies. The oxygen reduction reaction occurs at the surface of electrocatalytic materials, and since nanomaterial structures exhibit different catalytic activities, their shapes have a strong relationship to the final performance. Seed-mediated synthesis can be used to control the shape of materials with the aim of obtaining products with the most desirable surface properties for the ORR. This review summarized the current advancement of the synthesis of platinum-based ORR and provided the insights for the future development of this field.

Type: Article
Title: Seed-Mediated, Shape-Controlled Synthesis Methods for Platinum-Based Electrocatalysts for the Oxygen Reduction Reaction—A Mini Review
Open access status: An open access version is available from UCL Discovery
DOI: 10.3389/fchem.2022.865214
Publisher version: https://doi.org/10.3389/fchem.2022.865214
Language: English
Additional information: © 2022 Gray, Munshi, Scowen, Brett and He. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
Keywords: platinum, electrocatalysts, hydrogen fuel cell, oxygen reduction reaction, shapecontrolled, seed-mediated
UCL classification: UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/10146929
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