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Mass transport in PEM water electrolysers: A review

Maier, M; Smith, K; Dodwell, J; Hinds, G; Shearing, PR; Brett, DJL; (2022) Mass transport in PEM water electrolysers: A review. International Journal of Hydrogen Energy , 47 (1) pp. 30-56. 10.1016/j.ijhydene.2021.10.013. Green open access

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Abstract

While hydrogen generation by alkaline water electrolysis is a well-established, mature technology and currently the lowest capital cost electrolyser option; polymer electrolyte membrane water electrolysers (PEMWEs) have made major advances in terms of cost, efficiency, and durability, and the installed capacity is growing rapidly. This makes the technology a promising candidate for large-scale hydrogen production, and especially for energy storage in conjunction with renewable energy sources – an application for which PEMWEs offer inherent advantages over alkaline electrolysis. Improvements in PEMWE technology have led to increasingly high operational current densities, which requires adequate mass transport strategies to ensure sufficient supply of reactant and removal of products. This review discusses the current knowledge related to mass transport and its characterisation/diagnosis for PEMWEs, considering the flow channels, liquid-gas diffusion layer, and polymer electrolyte membrane in particular.

Type: Article
Title: Mass transport in PEM water electrolysers: A review
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.ijhydene.2021.10.013
Publisher version: https://doi.org/10.1016/j.ijhydene.2021.10.013
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: PEM Water electrolyser, Mass transport, Flow channels, Liquid-gas diffusion layer, Two-phase flow
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering
URI: https://discovery.ucl.ac.uk/id/eprint/10140633
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