Chen, L;
van Muyden, AP;
Cui, X;
Fei, Z;
Yan, N;
Laurenczy, G;
Dyson, PJ;
(2021)
Lignin First: Confirming the Role of the Metal Catalyst in Reductive Fractionation.
JACS Au
, 1
(6)
pp. 729-733.
10.1021/jacsau.1c00018.
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Abstract
Rhodium nanoparticles embedded on the interior of hollow porous carbon nanospheres, able to sieve monomers from polymers, were used to confirm the precise role of metal catalysts in the reductive catalytic fractionation of lignin. The study provides clear evidence that the primary function of the metal catalyst is to hydrogenate monomeric lignin fragments into more stable forms following a solvent-based fractionation and fragmentation of lignin.
| Type: | Article |
|---|---|
| Title: | Lignin First: Confirming the Role of the Metal Catalyst in Reductive Fractionation |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1021/jacsau.1c00018 |
| Publisher version: | https://doi.org/10.1021/jacsau.1c00018 |
| Language: | English |
| Additional information: | This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
| Keywords: | Reductive catalytic fractionation, Lignin first, Solvolysis, Rhodium, Sustainable chemistry |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10138159 |
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