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An experimental and modelling study of dual fuel aqueous ammonia and diesel combustion in a single cylinder compression ignition engine

Frost, J; Tall, A; Sheriff, AM; Schönborn, A; Hellier, P; (2021) An experimental and modelling study of dual fuel aqueous ammonia and diesel combustion in a single cylinder compression ignition engine. International Journal of Hydrogen Energy , 46 (71) pp. 35495-35510. 10.1016/j.ijhydene.2021.08.089. Green open access

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Abstract

The ability of ammonia to act as a hydrogen carrier, without the drawbacks of hydrogen gas-storage costs and low stability-renders it a potential solution to the decarbonisation of transport. This study combines both modelling and experimental techniques to determine the effect of varying the degree of aspiration of ammonium hydroxide (NH4OH) solution, at different engine loads, in the combustion of a compression ignition engine. Ignition delay was extended as ammonia injection increased, causing an increase in peak in-cylinder temperature, but generally lower combustion quality-increasing incomplete combustion products, while decreasing particle size. The higher peak in-cylinder temperatures generally correlated with a higher nitrous oxide (NOx) emissions in the exhaust, though fuel-bound nitrogen effect was apparent. Chemical kinetic modelling at equivalent conditions found increasing levels of unburnt ammonia with greater aspiration. Moreover, the ignitability of NH4OH was found to improve in simulations substituting diesel with hydrogen peroxide direct injection.

Type: Article
Title: An experimental and modelling study of dual fuel aqueous ammonia and diesel combustion in a single cylinder compression ignition engine
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.ijhydene.2021.08.089
Publisher version: https://doi.org/10.1016/j.ijhydene.2021.08.089
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: Ammonia Combustion, Compression Ignition, NOx and Particle Emissions, Low-carbon fuel
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Mechanical Engineering
URI: https://discovery.ucl.ac.uk/id/eprint/10135984
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