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The spectrum of ammonia near 0.793 μm

Zobov, NF; Bertin, T; Vander Auwera, J; Civiš, S; Knížek, A; Ferus, M; Ovsyannikov, RI; ... Polyansky, OL; + view all (2021) The spectrum of ammonia near 0.793 μm. Journal of Quantitative Spectroscopy and Radiative Transfer , 273 , Article 107838. 10.1016/j.jqsrt.2021.107838. Green open access

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Abstract

Two sets of NH3 absorption spectra covering the 0.793 μm region are recorded using two Bruker IFS 125 HR Fourier transform spectrometers. Three unapodized absorption spectra are recorded in Brussels over the range 11000−14500 cm−1 and the positions and intensities of 1114 ammonia lines observed in the 12491−12810 cm−1 region are measured using a multi-spectrum least squares fitting algorithm. 367 additional lines are identified in an ammonia absorption spectrum recorded in two steps at the J. Heyrovsky Institute of Physical Chemistry in Prague, using two different interference filters covering the 12000−12500 and 12400−13000 cm−1 ranges. The 1481 measured ammonia lines are analyzed using an empirical line list computed using variational nuclear motion calculations and ground state combination differences. Transitions are assigned to vibrational states with 4νNH stretching excitation (v1+v3=4). 278 out of the 1481 measured lines are assigned to 300 transitions and 119 upper state energy levels are derived from the frequencies of the assigned transitions.

Type: Article
Title: The spectrum of ammonia near 0.793 μm
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.jqsrt.2021.107838
Publisher version: https://doi.org/10.1016/j.jqsrt.2021.107838
Language: English
Additional information: © 2021 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/)
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery.ucl.ac.uk/id/eprint/10133058
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