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Slow Decay Processes of Electrostatically Trapped Rydberg NO Molecules

Deller, A; Rayment, MH; Hogan, SD; (2020) Slow Decay Processes of Electrostatically Trapped Rydberg NO Molecules. Physical Review Letters , 125 (7) , Article 073201. 10.1103/PhysRevLett.125.073201. Green open access

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Abstract

Nitric oxide (NO) molecules initially traveling at 795 m/s in pulsed supersonic beams have been photoexcited to long-lived hydrogenic Rydberg-Stark states, decelerated and electrostatically trapped in a cryogenically cooled, chip-based transmission-line Rydberg-Stark decelerator. The decelerated and trapped molecules were detected in situ by pulsed electric field ionization. The operation of the decelerator was validated by comparison of the experimental data with the results of numerical calculations of particle trajectories. Studies of the decay of the trapped molecules on timescales up to 1 ms provide new insights into the lifetimes of, and effects of blackbody radiation on, Rydberg states of NO.

Type: Article
Title: Slow Decay Processes of Electrostatically Trapped Rydberg NO Molecules
Open access status: An open access version is available from UCL Discovery
DOI: 10.1103/PhysRevLett.125.073201
Publisher version: https://doi.org/10.1103/PhysRevLett.125.073201
Language: English
Additional information: This version is the version of record. For information on re-use, please refer to the publisher's terms and conditions.
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery.ucl.ac.uk/id/eprint/10109075
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