Schotten, C;
Leprevost, SK;
Yong, LM;
Hughes, CE;
Harris, KDM;
Browne, DL;
(2020)
Comparison of the Thermal Stabilities of Diazonium Salts and Their Corresponding Triazenes.
Organic Process Research and Development
, 24
(10)
pp. 2336-2341.
10.1021/acs.oprd.0c00162.
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Abstract
A range of diazonium salts and their corresponding triazenes have been prepared in order to directly compare their relative thermal stabilities (via initial decomposition temperature) from differential scanning calorimetry (DSC) data. A structure–stability relationship has been explored to investigate trends in stability, depending on the aromatic substituent and the structure of the secondary amine component of the diazonium salts and triazenes. All of the triazenes investigated show significantly greater stability (many are stable above 200 °C) compared with the corresponding diazonium salts, which show varying stabilities.
| Type: | Article |
|---|---|
| Title: | Comparison of the Thermal Stabilities of Diazonium Salts and Their Corresponding Triazenes |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1021/acs.oprd.0c00162 |
| Publisher version: | https://doi.org/10.1021/acs.oprd.0c00162 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | triazene, diazonium salt, thermal stability, DSC, continuous processing |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences > UCL School of Pharmacy UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences > UCL School of Pharmacy > Pharma and Bio Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10098662 |
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