Reocreux, R;
Uhlman, M;
Thuening, T;
Paul, K;
Ryan, H;
Stamatakis, M;
Sykes, C;
(2019)
Efficient and Selective Carbon-Carbon Coupling on Coke-Resistant PdAu Single-Atom Alloys.
Chemical Communications
, 55
pp. 15085-15088.
10.1039/C9CC07932G.
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Abstract
We demonstrate that PdAu single-atom alloy model catalysts offer a heterogeneous route to selective Würtz-type C–C coupling. Specifically, when methyl iodide is exposed to an otherwise unreactive Au(111) surface, single Pd atoms in the surface layer promote C–I dissociation and C–C coupling, leading to the selective formation of ethane.
| Type: | Article |
|---|---|
| Title: | Efficient and Selective Carbon-Carbon Coupling on Coke-Resistant PdAu Single-Atom Alloys |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/C9CC07932G |
| Publisher version: | https://doi.org/10.1039/C9CC07932G |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10086108 |
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