Roffey, A; Hollingsworth, N; Hogarth, G; (2019) Synthesis of ternary sulfide nanomaterials using dithiocarbamate complexes as single source precursors. Nanoscale Advances , 1 (8) pp. 3056-3066. 10.1039/c9na00275h.

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Abstract

We report the use of cheap, readily accessible and easy to handle di-isobutyl-dithiocarbamate complexes, [M(S2CNi Bu2)n], as single source precursors (SSPs) to ternary sulfides of iron–nickel, iron–copper and nickel–cobalt. Varying decomposition temperature and precursor concentrations has a significant effect on both the phase and size of the nanomaterials, and in some instances meta-stable phases are accessible. Decomposition of [Fe(S2CNi Bu2)3]/[Ni(S2CNi Bu2)2] at ca. 210–230 �C affords metastable FeNi2S4 (violarite) nanoparticles, while at higher temperatures the thermodynamic product (Fe,Ni)9S8 (pentlandite) results. Addition of tetra-isobutyl-thiuram disulfide to the decomposition mixture can significantly affect the nature of the product at any particular temperature-concentration, being attributed to suppression of the intramolecular Fe(III) to Fe(II) reduction. Attempts to replicate this simple approach to ternary metal sulfides of iron–indium and iron–zinc were unsuccessful, mixtures of binary metal sulfides resulting. Oleylamine is non-innocent in these transformations, and we propose that SSP decomposition occurs via primary–secondary backbone amide-exchange with primary dithiocarbamate complexes, [M(S2CNHoleyl)n], being the active decomposition precursors.

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