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SERS-Active Cu Nanoparticles on Carbon Nitride Support Fabricated Using Pulsed Laser Ablation

Dizajghorbani-Aghdam, H; Miller, TS; Malekfar, R; McMillan, PF; (2019) SERS-Active Cu Nanoparticles on Carbon Nitride Support Fabricated Using Pulsed Laser Ablation. Nanomaterials , 9 (9) , Article 1223. 10.3390/nano9091223. Green open access

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Abstract

We report a single-step route to co-deposit Cu nanoparticles with a graphitic carbon nitride (gCN) support using nanosecond Ce:Nd:YAG pulsed laser ablation from a Cu metal target coated using acetonitrile (CH3CN). The resulting Cu/gCN hybrids showed strong optical absorption in the visible to near-IR range and exhibited surface-enhanced Raman or resonance Raman scattering (SERS or SERRS) enhancement for crystal violet (CV), methylene blue (MB), and rhodamine 6G (R6G) used as probe analyte molecules adsorbed on the surface. We have characterized the Cu nanoparticles and the nature of the gCN support materials using a range of spectroscopic, structural, and compositional analysis techniques.

Type: Article
Title: SERS-Active Cu Nanoparticles on Carbon Nitride Support Fabricated Using Pulsed Laser Ablation
Open access status: An open access version is available from UCL Discovery
DOI: 10.3390/nano9091223
Publisher version: https://doi.org/10.3390/nano9091223
Language: English
Additional information: This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Keywords: pulsed laser ablation; acetonitrile (CH3CN); Cu/gCN hybrids; localized surface plasmon resonance (LSPR); surface enhanced Raman scattering (SERS); surface enhanced resonance Raman scattering (SERRS)
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/10080920
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