Yücesan, G;
Maares, M;
Ayhan, MM;
Yu, KB;
Yazaydin, AO;
Harmandar, K;
Haase, H;
... Zorlu, Y; + view all
(2019)
Alkali‐phosphonate‐MOFs.
Chemistry. A European Journal
, 25
(48)
pp. 11214-11217.
10.1002/chem.201902207.
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Abstract
We report a new family of porous MOFs namely alkali-phosphonate-MOFs. [Na2Cu(H4TPPA)]·(NH2(CH3)2)2 (GTUB-1) was synthesized using the tetratopic 5,10,15,20-Tetrakis[p-phenylphosphonic acid] porphyrin (H8-TPPA) linker with planar X-shaped geometrical core. GTUB-1 is composed of rectangular void channels with BET surface area of 697 m2/g. GTUB-1 exhibits exceptional thermal stability. The toxicity analysis of the (H8-TPPA) linker indicates that it is well tolerated by an intestinal cell line, suggesting its suitability for creating phosphonate-MOFs for biological applications.
| Type: | Article |
|---|---|
| Title: | Alkali‐phosphonate‐MOFs |
| Location: | Germany |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1002/chem.201902207 |
| Publisher version: | https://doi.org/10.1002/chem.201902207 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | porphyrin, alkali-phosphonate MOFs, toxicology, thermal stability |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10075506 |
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