Meyer, Q;
Hack, J;
Mansor, N;
Iacoviello, F;
Bailey, JJ;
Shearing, PR;
Brett, DJL;
(2019)
Multi-Scale Imaging of Polymer Electrolyte Fuel Cells using X-ray Micro- and Nano-Computed Tomography, Transmission Electron Microscopy and Helium-Ion Microscopy.
Fuel Cells
, 19
(1)
pp. 35-42.
10.1002/fuce.201800047.
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Abstract
Multi‐length scale imaging of polymer electrolyte fuel cell (PEFC) membrane electrode assembly (MEA) materials is a powerful tool for studying, understanding and furthering improvements in materials engineering, performance and durability. A hot pressed MEA has been imaged using X‐ray micro‐ and nano‐computed tomography (CT), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and recently developed helium‐ion microscopy (HeIM). X‐ray nano‐CT captures a volume containing all of the relevant fuel cell interfaces, from the carbon fiber of the gas diffusion layer (GDL) to the Nafion membrane with a field‐of‐view of 5 µm and a pixel size of 64 nm. Features identified include linear marks on the carbon fiber surface, agglomerates of carbon nanoparticles in the microporous layer (MPL), and intrusion of the catalyst layer material into the Nafion membrane during the hot‐pressing process. HeIM has enabled imaging of a large area of MEA from tens of micrometers to sub‐nanometers pixel resolution without any sample preparation, and has captured similar features to X‐ray micro‐CT and nano‐CT. Furthermore, at its highest resolution, the platinum and carbon catalyst nanoparticles can be distinguished at the surface of the catalyst layer, overcoming the limitations of SEM and TEM.
| Type: | Article |
|---|---|
| Title: | Multi-Scale Imaging of Polymer Electrolyte Fuel Cells using X-ray Micro- and Nano-Computed Tomography, Transmission Electron Microscopy and Helium-Ion Microscopy |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1002/fuce.201800047 |
| Publisher version: | https://doi.org/10.1002/fuce.201800047 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | Catalyst, Gas Diffusion Layer, Helium-ion Micro-scopy, Membrane Electrode Assembly, Transmission Elec-tron Microscopy, X-ray Computed Tomography |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Electronic and Electrical Eng |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10072119 |
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