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Heterostructured WO3@CoWO4 bilayer nanosheets for enhanced visible-light photo, electro and photoelectro-chemical oxidation of water

Zhang, H; Tian, W; Li, Y; Sun, H; Tade, MO; Wang, S; (2018) Heterostructured WO3@CoWO4 bilayer nanosheets for enhanced visible-light photo, electro and photoelectro-chemical oxidation of water. Journal of Materials Chemistry A , 6 (15) pp. 6265-6272. 10.1039/c8ta00555a. Green open access

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Abstract

Herein, a facile interface-induced synthesis method is first established to newly fabricate two-dimensional (2D) bilayer nanosheets of WO3@CoWO4 as highly efficient catalysts for enhanced photo, electro and photoelectro-chemical oxygen evolution reactions (OERs). The heterostructure and the interfacial oxygen vacancy of WO3@CoWO4 reduce the energy barriers in the OER. Density functional theory (DFT) calculations and material characterizations reveal that the WO3@CoWO4 p–n heterojunction endows the composite with a narrowed band gap for better visible-light harvesting, rapid charge transfer across the interface and a lower recombination rate of the photo-excited carriers. The interface O-vacancy vests the active Co site with an enhanced density of state (DOS) at the valence band maximum (VBM), which can increase the concentration of the photogenerated holes to improve photocatalytic and photoelectrochemical (PEC) activity. This study presents a proof-of-concept design towards low cost and multi-metal 2D/2D nanosheets for water oxidation applications.

Type: Article
Title: Heterostructured WO3@CoWO4 bilayer nanosheets for enhanced visible-light photo, electro and photoelectro-chemical oxidation of water
Open access status: An open access version is available from UCL Discovery
DOI: 10.1039/c8ta00555a
Publisher version: https://doi.org/10.1039/c8ta00555a
Language: English
Additional information: This work is licensed under a Creative Commons Attribution 3.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/3.0/
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Earth Sciences
URI: https://discovery.ucl.ac.uk/id/eprint/10069139
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