Wang, F;
Mielby, J;
Richter, FH;
Wang, G;
Prieto, G;
Kasama, T;
Weidenthaler, C;
... Schueth, F; + view all
(2014)
A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity.
Angewandte Chemie - International Edition
, 53
(33)
pp. 8645-8648.
10.1002/anie.201404912.
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Abstract
We describe a solid polyphenylene support that serves as an excellent platform for metal‐catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium‐catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non‐activated substrates that are challenging even for molecular catalysts.
| Type: | Article |
|---|---|
| Title: | A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1002/anie.201404912 |
| Publisher version: | https://doi.org/10.1002/anie.201404912 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | Science & Technology, Physical Sciences, Chemistry, Multidisciplinary, Chemistry, cross-coupling, nanoparticles, polymer supports, polyphenylenes, CROSS-COUPLING REACTIONS, ARYL CHLORIDES, AEROBIC OXIDATION, ROOM-TEMPERATURE, SUZUKI-MIYAURA, PALLADIUM, NANOPARTICLES, METAL, POLYCONDENSATION, NANOCLUSTERS |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10065548 |
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