Diez, SJ;
Eddleston, MD;
Arhangelskis, M;
Milbled, M;
Müller, MJ;
Bond, AD;
Bučar, DK;
(2018)
Crystallization at Solvent Interfaces Enables Access to a Variety of Cocrystal Polymorphs and Hydrates.
Crystal Growth and Design
, 18
(6)
pp. 3263-3268.
10.1021/acs.cgd.8b00114.
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Abstract
A crystal growth technique, interfacial cocrystallization, is demonstrated to be a simple and effective method for preparing multicomponent crystal forms. The technique is based on the generation of a liquid-liquid interface between two immiscible solutions of cocrystal-forming compounds, and its utility is demonstrated through the preparation of polymorphs and hydrates of caffeine cocrystals, involving three different hydroxy-2-naphthoic acids, including the formation of some with unexpected compositions.
| Type: | Article |
|---|---|
| Title: | Crystallization at Solvent Interfaces Enables Access to a Variety of Cocrystal Polymorphs and Hydrates |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1021/acs.cgd.8b00114 |
| Publisher version: | http://dx.doi.org/10.1021/acs.cgd.8b00114 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10053263 |
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