Akpinar, I;
Yazaydin, AO;
(2017)
Rapid and Efficient Removal of Carbamazepine from Water by UiO-67.
Industrial and Engineering Chemistry Research
, 56
(51)
pp. 15122-15130.
10.1021/acs.iecr.7b03208.
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Abstract
Carbamazepine is a persistent contaminant detected in surface and ground waters. In this study we present the adsorptive removal of carbamazepine from water in the metal–organic frameworks UiO-66 and UiO-67 in comparison with a commercial activated carbon F400. While UiO-66 was ineffective in removing carbamazepine, UiO-67 showed superior performance by removing 95% of carbamazepine from a 100 mg L–1 aqueous carbamazepine solution in just 2 min. In contrast, it took F400 more than an hour to remove 88% of the carbamazepine under the same conditions. We further show that UiO-67 can be regenerated repeatedly with no or negligible carbamazepine removal capacity loss, which demonstrates its potential as a durable and promising adsorbent that can be used for the removal of carbamazepine from water.
Type: | Article |
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Title: | Rapid and Efficient Removal of Carbamazepine from Water by UiO-67 |
Open access status: | An open access version is available from UCL Discovery |
DOI: | 10.1021/acs.iecr.7b03208 |
Publisher version: | http://dx.doi.org/10.1021/acs.iecr.7b03208 |
Language: | English |
Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
Keywords: | Science & Technology, Technology, Engineering, Chemical, Engineering, METAL-ORGANIC FRAMEWORKS, ENDOCRINE DISRUPTING COMPOUND, GRANULAR ACTIVATED CARBON, ADSORPTIVE REMOVAL, AQUEOUS-SOLUTION, WASTE-WATER, CLOFIBRIC ACID, EMERGING CONTAMINANTS, DICLOFENAC SODIUM, ENHANCED REMOVAL |
UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
URI: | https://discovery.ucl.ac.uk/id/eprint/10043711 |
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