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Development of a polymer electrolyte fuel cell dead-ended anode purge strategy for use with a nitrogen-containing hydrogen gas supply

Okedi, TI; Meyer, Q; Hunter, HMA; Shearing, PR; Brett, DJL; (2017) Development of a polymer electrolyte fuel cell dead-ended anode purge strategy for use with a nitrogen-containing hydrogen gas supply. International Journal of Hydrogen Energy , 42 (19) pp. 13850-13859. 10.1016/j.ijhydene.2016.11.081. Green open access

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Abstract

The effect of nitrogen content within the hydrogen fuel supplied to a polymer electrolyte fuel cell (PEFC) operating in dead-ended anode mode is examined, with a view to using an ammonia decomposition product gas mix (containing 75H2:25N2) as the hydrogen-containing fuel. The impact of this impure hydrogen stream, supplied to the anode, was evaluated in terms of mean cell voltage and in relation to actual operating conditions (purge interval, dead-ended interval and fuel cell load). Design of Experiments (DoE) methodology, using multi-linear models, assessed hydrogen utilisation in terms of stack efficiency and identified an effective and viable dead-ended anode purge strategy for this nitrogen-containing hydrogen fuel.

Type: Article
Title: Development of a polymer electrolyte fuel cell dead-ended anode purge strategy for use with a nitrogen-containing hydrogen gas supply
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.ijhydene.2016.11.081
Publisher version: http://dx.doi.org/10.1016/j.ijhydene.2016.11.081
Language: English
Additional information: This manuscript version is published under a Creative Commons Attribution Non-commercial Non-derivative 4.0 International licence (CC BY-NC-ND 4.0). This licence allows you to share, copy, distribute and transmit the work for personal and non-commercial use providing author and publisher attribution is clearly stated. Further details about CC BY licences are available at http://creativecommons.org/licenses/by/4.0. Access may be initially restricted by the publisher.
Keywords: Hydrogen; Nitrogen; Purge strategy; Dead-ended anode; Design of experiments; PEFC stack efficiency
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering
URI: https://discovery.ucl.ac.uk/id/eprint/1545059
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