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Lepidocrocite-like TiO2 and TiO2(110)–(1 × 2) supported on W(100)

Harrison, GT; Spadaro, MC; Pang, CL; Grinter, DC; Yim, CM; Luches, P; Thornton, G; (2016) Lepidocrocite-like TiO2 and TiO2(110)–(1 × 2) supported on W(100). Materials Science and Technology , 32 (3) pp. 203-208. 10.1179/1743284715Y.0000000086. Green open access

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Abstract

Ultrathin films of TiO2 were grown on a W(100)–O(2 × 1) substrate and characterised with a combination of scanning tunneling microscopy (STM) and low energy electron diffraction. In addition to islands of rutile TiO2(110) with (1 × 1) termination that were reported previously, we also observed rutile TiO2(110) islands with a (1 × 2) film termination. A lepidocrocite-like TiO2 nanosheet was also observed on the W(100) surface. High resolution STM images show that the nanosheet grows in the principal orthogonal directions of the W(100) substrate and forms a commensurate (1 × 7) coincident cell.

Type: Article
Title: Lepidocrocite-like TiO2 and TiO2(110)–(1 × 2) supported on W(100)
Open access status: An open access version is available from UCL Discovery
DOI: 10.1179/1743284715Y.0000000086
Publisher version: https://doi.org/10.1179/1743284715Y.0000000086
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/1469155
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