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Synthesis of TiO2(110) ultra-thin films on W(100) and their reactions with H2O

Matharu, J; Cabailh, G; Thornton, G; (2013) Synthesis of TiO2(110) ultra-thin films on W(100) and their reactions with H2O. SURFACE SCIENCE , 616 198 - 205. 10.1016/j.susc.2013.05.020. Green open access

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Abstract

We present a study of the growth and reactivity of ultra-thin films of TiO2 grown on W(100). Three approaches to film growth are investigated, each resulting in films that show order in low-energy diffraction (LEED) and a low level of non-stoichiometry in X-ray photoelectron spectroscopy (XPS). H2O is used as a probe of the reactivity of the films, with changes in the Ti 2p and O 1s core levels being monitored by XPS. Evidence for the dissociation of H2O on the TiO2(110) ultra-thin film surface is adduced. These results are discussed with reference to related studies on native TiO2(110).

Type: Article
Title: Synthesis of TiO2(110) ultra-thin films on W(100) and their reactions with H2O
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.susc.2013.05.020
Publisher version: http://dx.doi.org/10.1016/j.susc.2013.05.020
Additional information: © 2013 Elsevier B.V. All rights reserved. This work is licensed under a Creative Commons Attribution 3.0 Unported License.
Keywords: TiO2, Thin films, XPS, LEED, H2O
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/1421787
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