Edgar, JO;
Gould, JA;
Badreshany, K;
Telling, J;
(2022)
Mechanochemical generation of perchlorate.
Icarus
, 387
, Article 115202. 10.1016/j.icarus.2022.115202.
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Abstract
Perchlorate (ClO4−) is widespread in the solar system having been detected on Earth, on Mars, in chondrite meteorites and in lunar samples. On Mars, perchlorates expand the potential for habitable conditions by lowering the freezing point of liquid water in the formation of brines. In future manned space exploration their presence poses a hazard to human health, however, it also represents opportunities as a source of oxygen and fuel. Despite their prevalence, the mechanism(s) of perchlorate formation in different solar system environments are poorly understood. Here we demonstrate that perchlorate can be generated through the mechanical activation of silicates in the presence of chloride.
Type: | Article |
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Title: | Mechanochemical generation of perchlorate |
Open access status: | An open access version is available from UCL Discovery |
DOI: | 10.1016/j.icarus.2022.115202 |
Publisher version: | http://dx.doi.org/10.1016/j.icarus.2022.115202 |
Language: | English |
Additional information: | Copyright © 2022 The Authors. Published by Elsevier Inc. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). |
Keywords: | Geological processes; Regoliths; Mineralogy; Impact processes; Mars |
UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
URI: | https://discovery.ucl.ac.uk/id/eprint/10187654 |
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