Bhide, MA;
Mears, KL;
Carmalt, CJ;
Knapp, CE;
(2022)
Precursor design and impact of structure on the fabrication of materials.
In:
Nanomaterials via Single-Source Precursors: Synthesis, Processing and Applications.
(pp. 3-53).
Elsevier
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Abstract
This chapter summarizes a range of recently published main group and (primarily) first-row d-block precursor complexes that have been employed in the deposition of metal chalcogenide materials via atmosphere-assisted chemical vapor deposition. In particular the rational design of precursors and the chemistry underpinning their performance are our principal focus in this chapter. Ligand design and metal-ligand cooperativity remain especially important and can afford precursors with interesting reactivity and structures, cleaner decomposition, controlled thermal properties, and lower cost. With the ever-expanding field of functional materials, precursor design is a means to facilitate further development and discovery in the deposition of a range of materials.
| Type: | Book chapter |
|---|---|
| Title: | Precursor design and impact of structure on the fabrication of materials |
| ISBN-13: | 9780128203446 |
| DOI: | 10.1016/B978-0-12-820340-8.00014-9 |
| Publisher version: | https://doi.org/10.1016/B978-0-12-820340-8.00014-9 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | Precursors, Synthesis, Structural parameter, Geometry, Deposition, Oxides, Sulfides, Selenides, Main group metal precursors, Chemical vapor deposition |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10170833 |
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