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Light Rechargeable Lithium-Ion Batteries Using V2O5 Cathodes

Boruah, BD; Wen, B; De Volder, M; (2021) Light Rechargeable Lithium-Ion Batteries Using V2O5 Cathodes. Nano Letters , 21 (8) pp. 3527-3532. 10.1021/acs.nanolett.1c00298. Green open access

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Abstract

Solar energy is one of the most actively pursued renewable energy sources, but like many other sustainable energy sources, its intermittent character means solar cells have to be connected to an energy storage system to balance production and demand. To improve the efficiency of this energy conversion and storage process, photobatteries have recently been proposed where one of the battery electrodes is made from a photoactive material that can directly be charged by light without using solar cells. Here, we present photorechargeable lithium-ion batteries (Photo-LIBs) using photocathodes based on vanadium pentoxide nanofibers mixed with P3HT and rGO additives. These photocathodes support the photocharge separation and transportation process needed to recharge. The proposed Photo-LIBs show capacity enhancements of more than 57% under illumination and can be charged to ∼2.82 V using light and achieve conversion efficiencies of ∼2.6% for 455 nm illumination and ∼0.22% for 1 sun illumination.

Type: Article
Title: Light Rechargeable Lithium-Ion Batteries Using V2O5 Cathodes
Open access status: An open access version is available from UCL Discovery
DOI: 10.1021/acs.nanolett.1c00298
Publisher version: https://doi.org/10.1021/acs.nanolett.1c00298
Language: English
Additional information: This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Keywords: Science & Technology, Physical Sciences, Technology, Chemistry, Multidisciplinary, Chemistry, Physical, Nanoscience & Nanotechnology, Materials Science, Multidisciplinary, Physics, Applied, Physics, Condensed Matter, Chemistry, Science & Technology - Other Topics, Materials Science, Physics, Lithium-ion batteries, V2O5, photocathodes, photorechargeable batteries
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > MAPS Faculty Office
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > MAPS Faculty Office > Institute for Materials Discovery
URI: https://discovery.ucl.ac.uk/id/eprint/10141784
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