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Long-range attraction between charge-mosaic surfaces across water

Perkin, S; Kampf, N; Klein, J; (2006) Long-range attraction between charge-mosaic surfaces across water. PHYS REV LETT , 96 (3) , Article 038301. 10.1103/PhysRevLett.96.038301. Green open access

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Abstract

We have measured directly the forces across water between hydrophilic surfaces covered with a random mosaic of positive and negative charged domains. We find a strong, long-ranged attraction between them at a surface separation comparable with the charge domain size (many tens of nanometers). This attraction persists at higher salt concentration, but its range then becomes comparable to the Debye screening length. We attribute the attraction to correlation between negative and positive regions on opposing surfaces, facilitated by the lateral mobility of the charge patches on the surfaces.

Type: Article
Title: Long-range attraction between charge-mosaic surfaces across water
Open access status: An open access version is available from UCL Discovery
DOI: 10.1103/PhysRevLett.96.038301
Publisher version: http://dx.doi.org/10.1103/PhysRevLett.96.038301
Language: English
Additional information: © 2006 The American Physical Society
Keywords: MICA SURFACES, ELECTROLYTE-SOLUTIONS, HYDROPHOBIC SURFACES, SUBNANOMETER FILMS, HYDRATION FORCES, GLASS SURFACES, DOUBLE-LAYER, FLUIDITY, RELEASE
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
URI: https://discovery.ucl.ac.uk/id/eprint/9366
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