Gawronski, H;
Carrasco, J;
Michaelides, A;
Morgenstern, K;
(2008)
Manipulation and control of hydrogen bond dynamics in absorbed ice nanoclusters.
PHYS REV LETT
, 101
(13)
, Article 136102. 10.1103/PhysRevLett.101.136102.
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Abstract
Inelastic electron tunneling is used to explore the dynamics of ice nanoclusters adsorbed on Ag(111). The diffusion of entire nanoclusters or internal hydrogen bond rearrangement can be selectively controlled by injecting electrons either directly into the clusters themselves or indirectly ("indirect inelastic electron tunneling'') into the substrate at distances of up to 20 nm from them; a reaction probability that oscillates with the tip-cluster lateral distance presents evidence that surface state electrons mediate the excitation. Density functional theory calculations reveal a strong sensitivity of the computed activation energies of the individual processes to the applied electrical field.
| Type: | Article |
|---|---|
| Title: | Manipulation and control of hydrogen bond dynamics in absorbed ice nanoclusters |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1103/PhysRevLett.101.136102 |
| Publisher version: | http://dx.doi.org/10.1103/PhysRevLett.101.136102 |
| Language: | English |
| Additional information: | © 2008 The American Physical Society |
| Keywords: | SCANNING TUNNELING MICROSCOPE, SINGLE-MOLECULE CHEMISTRY, EXCITATION, SURFACE, SPECTROSCOPY, MODES |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy |
| URI: | https://discovery.ucl.ac.uk/id/eprint/168412 |
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