Bulut, A;
Zorlu, Y;
Wörle, M;
Çetinkaya, A;
Kurt, H;
Tam, B;
Yazaydın, AÖ;
... Yücesan, G; + view all
(2017)
Short Naphthalene Organophosphonate Linkers to Microporous Frameworks.
ChemistrySelect
, 2
(24)
pp. 7050-7053.
10.1002/slct.201701411.
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Abstract
We report two novel 3D porous metal-organophosphonate metal organic frameworks (MOFs) [{Cu(4, 4’-bpy)0.5(1,4-NDPA-H2)] (1), [{Cu2(4,4’-bpy)0.5}(1,4-NDPA)] (2) and a non-porous [{Cu(4, 4’-bpy)}(2,6-NDPA-H2)] (3) constructed using the structurally rigid 1,4-naphthalenediphosphonic acid (1,4-NDPA-H4) and 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4). 1 and 2 exhibit high surface areas obtained using the structurally rigid and short aromatic organophosphonate linkers with copper. The compound 1 has been further analyzed by TGA and Quantum Design PPMS vibrating sample magnetometer.
| Type: | Article |
|---|---|
| Title: | Short Naphthalene Organophosphonate Linkers to Microporous Frameworks |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1002/slct.201701411 |
| Publisher version: | http://doi.org/10.1002/slct.201701411 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | Ligand Synthesis; Magnetism; Metal Organic Frameworks; Porous Solids; Synthesis by Design |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
| URI: | https://discovery.ucl.ac.uk/id/eprint/1572282 |
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