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GaAsP Nanowires and Nanowire Devices Grown on Silicon Substrates

Zhang, Y; Aagesen, M; Sanchez, AM; Beanland, R; Wu, J; Liu, H; (2017) GaAsP Nanowires and Nanowire Devices Grown on Silicon Substrates. In: Razeghi, M, (ed.) Proceedings Volume 10111, Quantum Sensing and Nano Electronics and Photonics XIV. SPIE: California, United States. Green open access

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Abstract

Ternary GaAsP nanowires (NWs) have gained great attention due to their structure-induced novel properties and band gap that can cover the working wavelength from green to infrared. However, the growth and hence applications of selfcatalyzed GaAsP NWs are troubled by the difficulties in controlling P and the complexities in growing ternary NWs. In this work, self-catalyzed core-shell GaAsP NWs were successfully grown and demonstrated almost stacking-fault-free zinc blend crystal structure. By using these core-shell GaAsP NWs, single NW solar cells have been fabricated and a single NW world record efficiency of 10.2% has been achieved. Those NWs also demonstrated their potential application in water splitting. A wafer-scale solar-to-hydrogen conversion efficiency of 0.5% has been achieved despite the low surface coverage. These results open up new perspectives for integrating III−V nanowire photovoltaics on a silicon platform by using self-catalyzed GaAsP core−shell nanowires.

Type: Proceedings paper
Title: GaAsP Nanowires and Nanowire Devices Grown on Silicon Substrates
Event: Conference on Quantum Sensing and Nano Electronics and Photonics XIV
Location: San Francisco, CA
Dates: 29 January 2017 - 02 February 2017
Open access status: An open access version is available from UCL Discovery
DOI: 10.1117/12.2250588
Publisher version: https://doi.org/10.1117/12.2250588
Language: English
Additional information: This version is the version of record. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: self-catalyzed, GaAsP, Nanowire
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Electronic and Electrical Eng
URI: https://discovery.ucl.ac.uk/id/eprint/1571880
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