Schuetrumpf, A;
Bulut, A;
Hermer, N;
Zorlu, Y;
Kirpi, E;
Stock, N;
Yazaydin, AO;
... Beckmann, J; + view all
(2017)
From Tetrahedral Tetraphosphonic Acids E[p-C6H4P(O)(OH)(2)](4) (E=C, Si) to Porous Cu- and Zn-MOFs with Large Surface Areas.
ChemistrySelect
, 2
(10)
pp. 3035-3038.
10.1002/slct.201700573.
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Abstract
This study describes the porous MOFs Cu2H4STPPA⋅2 H2O (1⋅2 H2O), Zn2H4STPPA (2) and Zn2H4MTPPA (3) obtained using the tetrahedral linkers tetraphenylmethane tetrakis-4-phosphonic acid (H8MTTPA) and tetraphenylsilane tetrakis-4-phosphonic acid (H8STPPA) under solvothermal conditions. X-ray structures reveal 3D frameworks with large assessable voids. The percentage void volumes and the specific BET surface areas of 1 (48.7 %, 794 m2/g), 2 (48.1 %, 565 m2/g) and 3 (51.3 %, 927 m2/g) predicted by molecular simulations are among the highest reported for MOFs derived from phosphonic acids.
| Type: | Article |
|---|---|
| Title: | From Tetrahedral Tetraphosphonic Acids E[p-C6H4P(O)(OH)(2)](4) (E=C, Si) to Porous Cu- and Zn-MOFs with Large Surface Areas |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1002/slct.201700573 |
| Publisher version: | http://dx.doi.org/10.1002/slct.201700573 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | Ligand Design; Metal Organic Solids; MOF; Organophosphonates |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
| URI: | https://discovery.ucl.ac.uk/id/eprint/1554773 |
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