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Intermolecular Interactions between Encapsulated Aromatic Compounds and the Host Framework of a Crystalline Sponge

Hayes, LM; Press, NJ; Tocher, DA; Carmalt, CJ; (2017) Intermolecular Interactions between Encapsulated Aromatic Compounds and the Host Framework of a Crystalline Sponge. Crystal Growth and Design , 17 (2) pp. 858-863. 10.1021/acs.cgd.6b01694. Green open access

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Abstract

The crystalline sponge [{(ZnI2)3(tris(4-pyridyl)-1,3,5-triazine)2·x(solvent)}n] has been used to produce a range of novel encapsulation compounds with acetophene, trans-cinnamaldehyde, naphthalene, anthracene, and benzylcyanide. Using additional data from previously reported encapsulation compounds, three systematic series have been created and analyzed to investigate the behavior of guest molecules within the sponge framework and identify the dominant intermolecular interactions.

Type: Article
Title: Intermolecular Interactions between Encapsulated Aromatic Compounds and the Host Framework of a Crystalline Sponge
Open access status: An open access version is available from UCL Discovery
DOI: 10.1021/acs.cgd.6b01694
Publisher version: http://dx.doi.org/10.1021/acs.cgd.6b01694
Language: English
Additional information: © 2016 American Chemical Society. This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Keywords: Science & Technology, Physical Sciences, Technology, Chemistry, Multidisciplinary, Crystallography, Materials Science, Multidisciplinary, Chemistry, Materials Science, POROUS COMPLEXES, MOLECULES, GUESTS
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/1545257
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