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Complex formation of dioxovanadium(V) with glycine and some glycyl peptides

Gharib, F; Nasiri, R; (2005) Complex formation of dioxovanadium(V) with glycine and some glycyl peptides. Reviews in Inorganic Chemistry , 25 (1) pp. 79-91. 10.1515/REVIC.2005.25.1.79. Green open access

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Abstract

Stability constants for complexes between dioxovanadium(V) and glycine, glycylglycine, glycylalanine, and giycylphenylalanine have been determined by a combination of Potentiometrie and spectrophotometries techniques in aqueous solution at 25 °C and 0.1 mol dm" ionic strength (NaClOj). Complex distribution curve depending on pH and metal-ligand ratio is given and influences of the side chains on the stability constants and the stoichiometrics of the formed complexes are given and discussed.

Type: Article
Title: Complex formation of dioxovanadium(V) with glycine and some glycyl peptides
Open access status: An open access version is available from UCL Discovery
DOI: 10.1515/REVIC.2005.25.1.79
Publisher version: https://doi.org/10.1515/REVIC.2005.25.1.79
Language: English
Additional information: This version is the version of record. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: Science & Technology, Physical Sciences, Chemistry, Inorganic & Nuclear, Chemistry, ionic-strength dependence, amino-acids, stability-constants, ternary complexes, side-chains, vanadium(v), oxovanadium(iv), systems, dipeptide, binding
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
URI: https://discovery.ucl.ac.uk/id/eprint/1545202
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