Szulc, BR;
Sil, BC;
Ruiz, A;
Hilton, ST;
(2015)
A Common Precursor Approach to Structurally Diverse Natural Products: The Synthesis of the Core Structure of (±)-Clausenamide and the Total Synthesis of (±)-Hyalodendrin.
European Journal of Organic Chemistry
, 2015
(34)
pp. 7438-7442.
10.1002/ejoc.201501256.
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Abstract
Structurally diverse natural products from unrelated sources typically require the development of individual synthetic routes. In a novel approach, we have shown that the epidithiodiketopiperazine-derived natural product (±)-hyalodendrin and the core structure of the unrelated pyrrolidine-derived natural product clausenamide can be synthesised from a common synthetic precursor in good yield by simple variation of the reaction conditions.
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