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Aerosol assisted chemical vapour deposition of transparent conductive aluminum-doped zinc oxide thin films from a zinc triflate precursor

Manzi, JA; Knapp, CE; Parkin, IP; Carmalt, CJ; (2016) Aerosol assisted chemical vapour deposition of transparent conductive aluminum-doped zinc oxide thin films from a zinc triflate precursor. Thin Solid Films , 616 pp. 477-481. 10.1016/j.tsf.2016.09.008. Green open access

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Abstract

The use of zinc triflate (trifluoromethanesulfonate), [Zn(OTf)2] as a precursor in the aerosol assisted chemical vapour deposition of zinc oxide thin films is described. Aluminum doped zinc oxide (AZO) thin films are also shown to be deposited when aluminum acetylacetonate [Al(acac)3] was introduced into the precursor solution, illustrating the versatility of this system. Film characterization techniques include glancing angle X-ray powder diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy and optical and electrical measurements. AZO films with an Al content of 7 at.% were found to have favourable transparent conducting oxide properties with simultaneous high transparency (> 80%) in the visible light region and a low electrical resistivity (1.96 × 10− 3 Ω cm).

Type: Article
Title: Aerosol assisted chemical vapour deposition of transparent conductive aluminum-doped zinc oxide thin films from a zinc triflate precursor
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.tsf.2016.09.008
Publisher version: http://doi.org/10.1016/j.tsf.2016.09.008
Language: English
Additional information: © 2016 Elsevier B.V. All rights reserved. This manuscript version is made available under a Creative Commons Attribution Non-commercial Non-derivative 4.0 International license (CC BY-NC-ND 4.0). This license allows you to share, copy, distribute and transmit the work for personal and non-commercial use providing author and publisher attribution is clearly stated. Further details about CC BY licenses are available at https://creativecommons.org/licenses/. Access may be initially restricted by the publisher.
Keywords: Science & Technology, Technology, Physical Sciences, Materials Science, Multidisciplinary, Materials Science, Coatings & Films, Physics, Applied, Physics, Condensed Matter, Materials Science, Physics, Zinc oxide, Zinc triflate, Transparent conducting oxide, Thin films, Aerosol assisted chemical vapour deposition, PULSED-LASER DEPOSITION, INDIUM-TIN-OXIDE, OPTICAL BAND-GAP, ZNO FILMS, ELECTRICAL-PROPERTIES, CVD, GROWTH, MOCVD, TEMPERATURE, FABRICATION
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/1534469
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