Brooks, AC;
Martin, L;
Day, P;
Clegg, W;
Harrington, RW;
Wallis, JD;
(2015)
New crystal packing arrangements in radical cation salts of BEDT-TTF with [Cr(NCS)6]3- and [Cr(NCS)5(NH3)]2-.
Polyhedron
, 102
pp. 75-81.
10.1016/j.poly.2015.07.013.
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Abstract
BEDT-TTF forms three packing arrangement styles in its radical cation salts with [Cr(NCS)6]3− in two of which two trans-oriented isothiocyanate ligands penetrate the BEDT-TTF layers either at the point where a solvent (nitrobenzene) is incorporated in a stack of donors or by four donor molecules forming a “tube” motif to accept a ligand at each end along with a small solvent molecule in between (acetonitrile). The [Cr(NCS)5NH3]2− ion forms a related crystal packing arrangement with BEDT-TTF with a reduction in the number of “tube” motifs needed to accept an isothiocyanate ligand.
Type: | Article |
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Title: | New crystal packing arrangements in radical cation salts of BEDT-TTF with [Cr(NCS)6]3- and [Cr(NCS)5(NH3)]2- |
Open access status: | An open access version is available from UCL Discovery |
DOI: | 10.1016/j.poly.2015.07.013 |
Publisher version: | http://dx.doi.org/10.1016/j.poly.2015.07.013 |
Language: | English |
Additional information: | © 2015 The Authors. Published by Elsevier Ltd. This is an open access article under the CCBY license (http://creativecommons.org/licenses/by/4.0/) |
Keywords: | BEDT-TTF, Chromium complexes, Crystal packing, Electrocrystallisation, Radical cation salts |
UCL classification: | UCL UCL > Provost and Vice Provost Offices UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
URI: | https://discovery.ucl.ac.uk/id/eprint/1472624 |
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