Mann, SE;
Benhamou, L;
Sheppard, TD;
(2015)
Palladium(II)-Catalysed Oxidation of Alkenes.
Synthesis
, 47
(20)
pp. 3079-3117.
10.1055/s-0035-1560465.
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Abstract
This review provides a summary of recent developments in the palladium(II)-catalysed oxidation of alkenes, focusing largely on reactions which lead to the formation of new carbon–oxygen or carbon–nitrogen bonds. Three classes of reaction are covered: i) oxidations proceeding via allylic C–H bond cleavage and formation of a π-allyl complex; ii) Wacker-type oxidations proceeding via nucleopalladation followed by β-hydride elimination; and iii) 1,2-difunctionalisation of alkenes proceeding via nucleopalladation followed by functionalisation of the resulting σ-alkylpalladium(II) intermediate. The mechanisms are discussed alongside the scope and limitations of each reaction.
| Type: | Article |
|---|---|
| Title: | Palladium(II)-Catalysed Oxidation of Alkenes |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1055/s-0035-1560465 |
| Publisher version: | http://dx.doi.org/10.1055/s-0035-1560465 |
| Language: | English |
| Additional information: | Alkenes, Oxidation, Palladium, Wacker oxidation, Catalysis |
| Keywords: | alkenes, oxidation, palladium, Wacker oxidation, catalysis |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/1472222 |
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