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X-ray micro-tomography as a diagnostic tool for the electrode degradation in vanadium redox flow batteries

Trogadas, P; Taiwo, OO; Tjaden, B; Neville, TP; Coppens, M-O; Brett, DJL; Shearing, PR; ... Ramani, V; + view all (2014) X-ray micro-tomography as a diagnostic tool for the electrode degradation in vanadium redox flow batteries. Electrochemistry Communications , 48 155 - 159. 10.1016/j.elecom.2014.09.010. Green open access

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Abstract

Micro-tomography (CT) can be successfully employed to characterize ex situ the structural changes occurring in graphite felt electrodes during vanadium redox flow battery (VRFB) operation. Coupled high resolution X-ray and electron microscopy in conjunction with XPS are used to elucidate the microstructural and chemical changes to the high voltage RFB carbon electrode. The results reveal the onset of corrosion of the carbon felt structure relatively early in the VRFB life-cycle, extended operation is expected to result in extensive microstructural evolution effects.

Type: Article
Title: X-ray micro-tomography as a diagnostic tool for the electrode degradation in vanadium redox flow batteries
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.elecom.2014.09.010
Publisher version: http://dx.doi.org/10.1016/j.elecom.2014.09.010
Language: English
Additional information: © 2014 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/3.0/).
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering
URI: https://discovery.ucl.ac.uk/id/eprint/1452685
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