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Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1'-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst.

Ghosh, S; Hogarth, G; Hollingsworth, N; Holt, KB; Kabir, SE; Sanchez, BE; (2014) Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1'-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst. Chem Commun (Camb) (50) pp. 945-947. 10.1039/c3cc46456c. Green open access

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Abstract

Fe2(CO)4(μ-dppf)(μ-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.

Type: Article
Title: Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1'-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst.
Open access status: An open access version is available from UCL Discovery
DOI: 10.1039/c3cc46456c
Publisher version: http://dx.doi.org/10.1039/c3cc46456c
Additional information: © The Royal Society of Chemistry 2014. This Open Access Article is licensed under a Creative Commons Attribution 3.0 Unported Licence
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/1422201
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