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Electron-impact resonant vibration excitation cross sections and rate coefficients for carbon monoxide

Laporta, V; Cassidy, CM; Tennyson, J; Celiberto, R; (2012) Electron-impact resonant vibration excitation cross sections and rate coefficients for carbon monoxide. Plasma Sources Sciences and Technology , 21 (4) , Article 045005. 10.1088/0963-0252/21/4/045005. Green open access

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Abstract

Resonant vibrational and rotation–vibration excitation cross sections for electron–CO scattering are calculated in the 0–10 eV energy range for all 81 vibrational states of CO, assuming that the excitation occurs via the 2Π shape resonance. Static exchange plus polarization calculations performed using the R-matrix method are used to estimate resonance positions and widths as functions of internuclear separation. The effects of nuclear motion are considered using a local-complex-potential model. Good agreement is obtained with available experimental data on excitation from the vibrational ground state. Excitation rates and cross sections are provided as a function of the initial CO vibrational state for all ground state vibrational levels.

Type: Article
Title: Electron-impact resonant vibration excitation cross sections and rate coefficients for carbon monoxide
Open access status: An open access version is available from UCL Discovery
DOI: 10.1088/0963-0252/21/4/045005
Publisher version: http://dx.doi.org/10.1088/0963-0252/21/4/045005
Language: English
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery.ucl.ac.uk/id/eprint/1353975
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