Augstein, BB; Faria, CFD; (2011) Influence of asymmetry and nodal structures on high-harmonic generation in heteronuclear molecules. J PHYS B-AT MOL OPT , 44 (5) , Article 055601. 10.1088/0953-4075/44/5/055601.

Preview

PDF 1009.0503v1.pdf Available under License : See the attached licence file. Download (1MB)

Abstract

The relation between high-harmonic spectra and the geometry of the molecular orbital in position and momentum space is investigated. In particular we choose two isoelectronic pairs of homonuclear and heteronuclear molecules, such that the highest occupied molecular orbital of the former exhibits at least one nodal plane. The imprint of such planes is a strong suppression in the harmonic spectra, for particular alignment angles. We are able to identify two distinct types of nodal structures. If, for homonuclear molecules, the nodal planes are determined by the atomic wavefunctions only, the angle for which the yield is suppressed will remain the same for both types of molecules. In contrast, if they are determined by the linear combination of atomic orbitals at different centers of the molecule, there will be a shift in the angle at which the suppression occurs and a distortion in the nodal structure for the heteronuclear molecule, with respect to its homonuclear counterpart. This shows that, in principle, molecular imaging, in which a homonuclear molecule is used as a reference while observing the wavefunction distortions in its heteronuclear counterpart, is possible.

Download activity - last month

Export as JSONXMLCSV

Download activity - last 12 months

Export as JSONXMLCSV

Downloads by country - last 12 months

Export as JSONCSVXML

Archive Staff Only

View Item