Joyeux, M.;
Sadovskií, D.A.;
Tennyson, J.;
(2003)
Monodromy of the LiNC/NCLi molecule.
Chemical Physics Letters
, 382
(3-4)
pp. 439-442.
10.1016/j.cplett.2003.10.099.
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Abstract
Using the potential surface of Essers, Tennyson, and Wormer in [Chem. Phys. Lett. 89 (1982) 223], we show that the system of bending vibrational states of the isomerizing molecule LiNC/NCLi has monodromy. On the basis of a deformed spherical pendulum model, we explain dynamical and geometric reasons of this phenomenon and of its absence in the similar system HCN/CNH.
| Type: | Article |
|---|---|
| Title: | Monodromy of the LiNC/NCLi molecule |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1016/j.cplett.2003.10.099 |
| Publisher version: | http://dx.doi.org/10.1016/j.cplett.2003.10.099 |
| Language: | English |
| UCL classification: | UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy |
| URI: | https://discovery.ucl.ac.uk/id/eprint/1286 |
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